Bismuth (Bi) — Z = 83

All ground‑state isotopes from A = 184…224 (no isomers in the main table; notable isomers are mentioned in notes). Primary data spine: NUBASE‑2020/Wikipedia “Isotopes of bismuth,” with point checks from LNHB/IAEA/KAERI where cited. (Wikipedia)

Abbreviations: = half‑life; α = alpha; β⁻/β⁺ = beta minus/plus; EC = electron capture; IT = isomeric transition; p = proton emission.
Origins: Natural = present in decay series (radiogenic) or primordial; Synthetic = accelerator/spallation products.

IsotopeZAStabilityMain decay(s) → daughterOriginNotes & uses
¹⁸⁴Bi83184Unstable6.6 msα → ¹⁸⁰TlSyntheticNuclear‑structure R. (Wikipedia)
¹⁸⁵Bi83185Unstable~2.8 μsp (≈92%) → ¹⁸⁴Pb; α (≈8%) → ¹⁸¹TlSyntheticNotable proton emitter (odd‑odd); modern PRL study on ¹⁸⁵Bi proton radioactivity. (Wikipedia)
¹⁸⁶Bi83186Unstable14.8 msα (≈99.99%) → ¹⁸²Tl; tiny β⁺, SFSyntheticR. (Wikipedia)
¹⁸⁷Bi83187Unstable37 msα → ¹⁸³TlSyntheticR. (Wikipedia)
¹⁸⁸Bi83188Unstable60 msα → ¹⁸⁴TlSyntheticR. (Wikipedia)
¹⁸⁹Bi83189Unstable688 msα → ¹⁸⁵TlSyntheticR. (Wikipedia)
¹⁹⁰Bi83190Unstable6.3 sα (77%) → ¹⁸⁶Tl; β⁺ (23%) → ¹⁹⁰PbSyntheticR. (Wikipedia)
¹⁹¹Bi83191Unstable12.4 sα (51%) → ¹⁸⁷Tl; β⁺ (49%) → ¹⁹¹PbSyntheticR. (Wikipedia)
¹⁹²Bi83192Unstable34.6 sβ⁺ (88%) → ¹⁹²Pb; α (12%) → ¹⁸⁸TlSyntheticR. (Wikipedia)
¹⁹³Bi83193Unstable63.6 sβ⁺ (96.5%) → ¹⁹³Pb; α (3.5%) → ¹⁸⁹TlSyntheticR. (Wikipedia)
¹⁹⁴Bi83194Unstable95 sβ⁺ (99.54%) → ¹⁹⁴Pb; α (0.46%) → ¹⁹⁰TlSyntheticR. (Wikipedia)
¹⁹⁵Bi83195Unstable183 sβ⁺ (99.97%) → ¹⁹⁵Pb; α (0.03%) → ¹⁹¹TlSyntheticR. (Wikipedia)
¹⁹⁶Bi83196Unstable5.13 minβ⁺ → ¹⁹⁶Pb; α (~1.15×10⁻³%) → ¹⁹²TlSyntheticR. (Wikipedia)
¹⁹⁷Bi83197Unstable9.33 minβ⁺ → ¹⁹⁷PbSyntheticR. (Wikipedia)
¹⁹⁸Bi83198Unstable10.3 minβ⁺ → ¹⁹⁸PbSyntheticR. (Wikipedia)
¹⁹⁹Bi83199Unstable27 minβ⁺ → ¹⁹⁹PbSyntheticR. (Wikipedia)
²⁰⁰Bi83200Unstable36.4 minβ⁺ → ²⁰⁰PbSyntheticR. (Wikipedia)
²⁰¹Bi83201Unstable103 minβ⁺ → ²⁰¹PbSyntheticR. (Wikipedia)
²⁰²Bi83202Unstable1.72 hβ⁺ → ²⁰²Pb (α <10⁻⁵)SyntheticR. (Wikipedia)
²⁰³Bi83203Unstable11.76 hβ⁺ → ²⁰³PbSyntheticR. (Wikipedia)
²⁰⁴Bi83204Unstable11.22 hβ⁺ → ²⁰⁴PbSyntheticRadiotracer in some Pb/Bi chemistry studies (R). (Wikipedia)
²⁰⁵Bi83205Unstable14.91 dβ⁺ → ²⁰⁵PbSyntheticR. (Wikipedia)
²⁰⁶Bi83206Unstable6.243 dβ⁺ → ²⁰⁶PbSyntheticR. (Wikipedia)
²⁰⁷Bi83207Unstable (long‑lived)31.22 yEC (±β⁺) → ²⁰⁷PbSyntheticWidely used γ/X‑ray calibration source (prominent 570, 1064, 1770 keV lines); NIST SRM and LNHB sheets. (NIST, gammaray.inl.gov, Lnhb)
²⁰⁸Bi83208Unstable (very long‑lived)3.68×10⁵ yEC/β⁺ → ²⁰⁸PbSyntheticLong‑lived EC nuclide; nuclear‑structure/background studies (R). (Wikipedia)
²⁰⁹Bi83209Very long‑lived2.01×10¹⁹ yα → ²⁰⁵TlNatural (mononuclidic Bi in nature)Formerly “stable”; α decay established with ~2×10¹⁹ y t½. Used chemically (e.g., Pb–Bi eutectic coolants); physics background studies. (Wikipedia)
²¹⁰Bi83210Unstable5.012 dβ⁻ → ²¹⁰Po (dominant); tiny α (≈1.3×10⁻⁴%) → ²⁰⁶TlNatural (U‑238 series)Part of the ²¹⁰Pb→²¹⁰Bi→²¹⁰Po chain; environmental/radon progeny studies; dating via ²¹⁰Pb. (Wikipedia, periodictable.com)
²¹¹Bi83211Unstable2.14 minα (99.72%) → ²⁰⁷Tl; β⁻ (0.276%) → ²¹¹PoNatural (U‑235 series)Short‑lived α source in actinium chain; precise decay data tabulated by LNHB. (Wikipedia, Lnhb)
²¹²Bi83212Unstable60.55 minβ⁻ (64.05%) → ²¹²Po; α (35.94%) → ²⁰⁸Tl; β⁻α (~0.014%) → ²⁰⁸PbNatural (Th‑232 series)Important branch point in thorium series; high‑quality evaluations exist. (Wikipedia, Lnhb)
²¹³Bi83213Unstable45.60 minβ⁻ (97.91%) → ²¹³Po; α (2.09%) → ²⁰⁹TlTrace in Np‑237 series; produced from ²²⁵AcTargeted α‑therapy nuclide (e.g., ²¹³Bi‑PSMA, antibody conjugates). (Wikipedia, PMC)
²¹⁴Bi83214Unstable19.9 minβ⁻ (≈99.98%) → ²¹⁴Po; α (~0.021%) → ²¹⁰Tl; β⁻α (~0.003%) → ²¹⁰PbNatural (U‑238/radon series)Environmental γ background lines at 609, 1120, 1764 keV; ubiquitous in radon studies & γ‑spectrometer calibration. (Wikipedia, www-nds.iaea.org, Lnhb, periodictable.com)
²¹⁵Bi83215Unstable7.62 minβ⁻ → ²¹⁵PoNatural (U‑235 series)R. (Wikipedia)
²¹⁶Bi83216Unstable2.21 minβ⁻ → ²¹⁶PoSynthetic / traceR. (Wikipedia)
²¹⁷Bi83217Unstable98.5 sβ⁻ → ²¹⁷PoSynthetic / traceR. (Wikipedia)
²¹⁸Bi83218Unstable33 sβ⁻ → ²¹⁸PoSynthetic / traceR. (Wikipedia)
²¹⁹Bi83219Unstable8.7 sβ⁻ → ²¹⁹PoSynthetic / traceR. (Wikipedia)
²²⁰Bi83220Unstable9.5 sβ⁻ → ²²⁰PoSynthetic / traceR. (Wikipedia)
²²¹Bi83221Unstable≳2 sβ⁻ → ²²¹Po (β⁻, n possible)SyntheticVery neutron‑rich; evaluated as β⁻ to Po. (Wikipedia, chemlin.org)
²²²Bi83222Unstable≳3 sβ⁻ → ²²²Po (expected)SyntheticVery limited data (near drip‑line); evaluated as β⁻ to Po. (Wikipedia)
²²³Bi83223Unstable≳1 sβ⁻ → ²²³Po (β⁻, n possible)SyntheticVery neutron‑rich; evaluated as β⁻ to Po. (Wikipedia, chemlin.org)
²²⁴Bi83224Unstable≳1 sβ⁻ → ²²⁴Po (β⁻, n possible)SyntheticVery neutron‑rich; evaluated as β⁻ to Po. (Wikipedia, chemlin.org)

Notable isomers (context only, not counted above). ²¹⁰ᵐBi has t½ ≈ 3.04×10⁶ y (extraordinarily long for an isomer); it primarily undergoes α → ²⁰⁶Tl or very slow IT/β⁻ paths. This does not change the ground‑state counting. (Wikipedia)


Element totals — Bismuth (Bi)

  • Ground‑state isotopes: 41 (A = 184–224). Stable: 0. Unstable: 41. (Wikipedia)
  • Natural members of decay chains: ²¹⁰Bi & ²¹⁴Bi (U‑238/radon series), ²¹¹Bi & ²¹⁵Bi (U‑235/actinium series), ²¹²Bi (Th‑232 series), ²¹³Bi (Np‑237 series, mostly accessed via ²²⁵Ac generators). (Wikipedia, NIST, isotopes.gov)

Running total across elements so far (H → Bi)

  • ≥2,691 ground‑state isotopes tabulated | Stable: 251 | Unstable: ≥2,439.
    (Increment here: +41 total, +0 stable, +41 unstable vs. the Pb line.)

Sources (key citations for this Bi table)

  • Master table & half‑lives/decay modes: “Isotopes of bismuth” (updated; includes NUBASE‑2020 references). (Wikipedia)
  • Bi‑209 α‑decay (2.01×10¹⁹ y): Wikipedia summary page; discovery reports and reviews. (Wikipedia)
  • Bi‑210 (chain membership & t½): NIST/U.S. radon series diagram; Wikipedia table. (periodictable.com, Wikipedia)
  • Bi‑211 precision decay data: LNHB (LNE–CEA) nuclide tables. (Lnhb)
  • Bi‑212 branching & t½: LNHB evaluation notes/tables. (Lnhb)
  • Bi‑213 in medicine (TAT): Reviews and clinical reports. (PMC)
  • Bi‑214 γ‑lines & t½: IAEA/LNHB sheets and spectrometry references. (www-nds.iaea.org, Lnhb, periodictable.com)
  • Neutron‑rich tails (²²¹–²²⁴Bi): Evaluated summaries (ChemLin) used for mode confirmation where Wikipedia’s table omits explicit mode text. (chemlin.org)
  • Bi‑207 calibration usage: NIST SRM sheet; detector calibration literature; LNHB comments. (NIST, gammaray.inl.gov, Lnhb)

Next element: Polonium (Po, Z = 84).